An efficient method for the N-arylation of phenylurea via copper catalyzed amidation
2011
Abstract The coupling reaction of phenylurea with different functionalized aryl halides in the presence of air stable CuI, N , N -dimethylethylenediamine as a ligand, and K 3 PO 4 as a base gives symmetrical and unsymmetrical diarylureas in relatively high yields. This method is milder than the palladium catalyzed arylation and avoids the use of toxic phosphine ligands.
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