One-Pot Thiourea Formation–Palladium-Catalyzed Cyclization Sequence to 3,4-Dihydro-2H-1,3-benzothiazine-2-imines from 2-Halo N-Methylbenzylamine – Scope and Limitations
2012
A practical synthesis of 3,4-dihydro-3-methyl-2 H -1,3-benzothiazine-2-imine via intramolecular palladium-catalyzed C–S bond formation is presented and exemplified for both alkyl- and arylisothiocyanates.
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