Diastereoselectivity Control in Formal Nucleophilic Substitution of Bromocyclopropanes with Oxygen- and Sulfur-Based Nucleophiles.

Joseph E. Banning,Anthony R. Prosser,Bassam K. Alnasleh,Jason Smarker,Marina Rubina,Michael Rubin

Diastereoselectivity Control in Formal Nucleophilic Substitution of Bromocyclopropanes with Oxygen- and Sulfur-Based Nucleophiles.

2011

Joseph E. Banning
Anthony R. Prosser
Bassam K. Alnasleh
Jason Smarker
Marina Rubina
Michael Rubin

The reaction of bromocyclopropanes with oxygen nucleophiles selectively provides trans- or cis-functionalized derivatives depending on the number and nature of cyclopropane substituents.

Keywords:

Cyclopropane
Oxygen
Substitution reaction
Nucleophile
Chemistry
Organic chemistry
Nucleophilic substitution
Sulfur

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