Convenient and highly efficient synthesis of boron–dipyrrins bearing an arylboronate center
2009
Novel boron–dipyrrins bearing an aryl group and a phenyloxy group linked directly to the boron center have been prepared in high yields from arylboronic acid. The unique coordination geometry around the boron was determined by an X-ray crystallographic analysis. The complexes showed a strong fluorescence, and alkylation of the OH group shifted the emission to a longer wavelength with a larger Stokes shift.
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