A study on the effects of anion, cation, organic compounds, and pH on the release behaviors of As and Sb from sediments.

The trace element of As and Sb have resulted in serious threats to ecological sustainability and human health in the Xijiang River basin, China. The geoaccumulation index (Igeo) results showed the sediment of Xijiang River was heavily contaminated by Sb as well as moderately contaminated by As. The effect of inorganic anions on the released As and Sb from the sediment increases in the following sequence: Cl- < SO42- < CO32- < PO43-. The presence of PO43- and CO32- had the greater effect over As mobility from the sediment compared to Sb. The effect of Ca(II), Al(III), and Mg(II) on the released amount of Sb from the sediment is negligible. Meanwhile, in the case of As, Ca(II) and Mg(II) had small impacts, but the released amount of As increased slightly with an increase of Al(III) concentration. The stability of As and Sb in the sediment was found to be the best at pH 5. The effect of organic compounds (≤ 0.05 mol/L) on the dissolved As percentages from the sediment increased in the following sequence: ethylenediaminetetraacetate (EDTA) < oxalate < citrate, and the effect on Sb release was oxalate < EDTA < citrate at concentrations (≤ 0.025 mol/L). This study provides the basic theoretical basis to manage the mobilization of co-contamination of sediments with As and Sb under the influence of external perturbations.