Cluster-based networks: assembly of a (4,4) layer and a rare T-shaped bilayer from [MnIII2MnII4O2(RCOO)10] coordination clusters
2014
The assembly of charge-neutral mixed-valent coordination clusters [MnIII2MnII4O2(RCOO)10] (R = CHMe2, CMe3) and rigid isonicotinamide or semi-rigid aldrithiol-4 exo-bridging ligands results in (4,4) layers and a 2D bilayer containing an unprecedented type of cluster-based ‘T-shaped’ motif.
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