Catalytic Activity of Aliphatic PNP Ligated CoIII/I Amine and Amido Complexes in Hydrogenation Reaction—Structure, Stability, and Substrate Dependence

Structures, energies, and stability of aliphatic PNP ligated CoIII/CoI amine and amido complexes in different spin (singlet, triplet, and open-shell singlet) states and coordination spheres have be...