EDTA-enhanced electrokinetic remediation of aged electroplating contaminated soil assisted by combining dual cation-exchange membranes and circulation methods

Abstract This paper introduces a novel method for ethylenediaminetetraacetic acid (EDTA)-enhanced electrokinetic (EK) remediation by combining dual cation-exchange membranes and circulation methods for an aged electroplating soil contaminated by chrome (Cr), copper (Cu), and nickel (Ni). Three laboratory-scale EK experiments were carried out, including T1, the traditional EK process; T2, the traditional EDTA-enhanced EK process; and T3, the assisted EDTA-enhanced EK process. The results obtained show that removal of Cu and Ni in T3 was 3–10 times higher than after T1 and T2. However, the removal of Cr (total) was small in all experiments because of the high content of Cr(III). T3 eliminated the metal accumulation problem that existed for T1 and T2. Simultaneously, the highly acidified area (pH