Structure and magnetic properties of TbMn6−xAlxSn6 compounds

In the present work, the influence of the substitution of Al for Mn on the structure and magnetic properties of TbMn6−xAlxSn6 compounds was investigated. With increasing Al concentration the lattice constants a, c, and the unit-cell volume V decrease monotonically. The TbMn6−xAlxSn6 compounds exhibit ferrimagnetic ordering. The magnetic ordering temperature first decreases with increasing Al content up to x=1.5, then increases with further increasing Al content. As for the unsubstituted material, it was found that this series of compounds exhibits a second magnetic transition at lower temperature that is attributed to spin reorientation. The spin-reorientation temperature and the magnetic anisotropy field first decrease with increasing Al content, go through a minimum at x=0.5, then increase with further increasing Al content. The saturation magnetization decreases monotonically with increasing Al content. Two metamagnetic transitions are found in TbMn6Sn6 compounds, one at 0.44 T, and the other at about ...