A high yielding route to substituted piperidines via the aza-Diels-Alder reaction

Patrick D. Bailey,Peter Smith,Frederick Pederson,William Clegg,Georgina M. Rosair,Simon J. Teat

A high yielding route to substituted piperidines via the aza-Diels-Alder reaction

2002

Patrick D. Bailey
Peter Smith
Frederick Pederson
William Clegg
Georgina M. Rosair
Simon J. Teat

Abstract The imine Ph 2 CHNCHCO 2 Et, generated from benzhydrylamine and ethyl glyoxylate, is an excellent dienophile in aza-Diels–Alder reactions, giving diastereomerically pure cycloadducts in high yield.

Keywords:

Glyoxylate cycle
Photochemistry
Diels–Alder reaction
Imine
Organic chemistry
Aza-Diels–Alder reaction
Chemistry

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