Process for producing porous structural materials metalorganic

Method for producing a porous structural material metallo comprising the step of reacting a reaction mixture in the liquid phase of at least one copper compound with at least one organic compound at least bidentate attachable coordinated manner copper, in the presence of a nonaqueous solvent, wherein the at least one organic compound at least bidentate is a tetracarboxylic trio acid producing reaction under atmospheric pressure in a range of 90 ° C to 150 ° C, the copper compound is one different from copper nitrate (II) and the nonaqueous solvent selected from the group consisting of C4-10 alkanol, dimethyl sulfoxide (DMSO), dimethylformamide (DMF), N, N-diethylformamide ( DEF), N, N-dimethylacetamide (DMAc), acetonitrile, toluene, dioxane, chlorobenzene, methyl ethyl ketone (MEK), pyridine, halogenated alkane C7-200 case optionally, sulfolane, alkylene, such as ethylene glycol, polyalkylene polyols such as polyethylene glycol, glycerin, N-methylpyrrolidone (NMP), gamma-butyrolactone, alicyclic alcohols such as cyclohexanol, ketones such as acetone or acetylacetone, cycloketones, as cyclohexanone, sulfoles or mixtures thereof.