Photoelectrochemical water splitting with a SrTiO3:Nb/SrTiO3 n+–n homojunction structure
2017
A very limited knowledge exists about the effect of non-uniform doping of epitaxially grown strontium titanate thin film electrodes on their photoelectrochemical performance in water splitting. In this work, water splitting photoanodes featuring an n+–n homojunction were fabricated by the pulsed laser deposition technique, where epitaxial SrTiO3 thin films were grown on Nb doped n+–SrTiO3 single crystalline substrates. Thermal diffusion of niobium from doped substrates into the deposited thin films formed an n+–n homojunction, which was profiled by angle-resolved XPS and cross-sectional STEM-EDX techniques. This homojunction was found to make a significant impact on the incident photon-to-current efficiency of photoanodes by affecting their depletion width, which was in agreement with the theoretical simulations.
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