Complete Reversal of Stereoselectivity in Cyclopropanation of 2- Arylidene-1-tetralone Tricarbonylchromium Complexes.

Sambasivam Ganesh,Kashinath M. Sathe,Malay Nandi,Pinak Chakrabarti,Amitabha Sarkar

Complete Reversal of Stereoselectivity in Cyclopropanation of 2- Arylidene-1-tetralone Tricarbonylchromium Complexes.

1993

Sambasivam Ganesh
Kashinath M. Sathe
Malay Nandi
Pinak Chakrabarti
Amitabha Sarkar

Cyclopropanation of 2-arylidene-1-tetralone tricarbonylchromium complexes with dimethylsulfoxonium methylide under phase-transfer catalysis condition provided cyclopropanes exclusively from the endo-face.

Keywords:

Cyclopropanation
1-Tetralone
Chemistry
Stereoselectivity
Organic chemistry

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