Morpholine‐based RAFT agents for the reversible deactivation radical polymerization of vinyl acetate and N ‐vinylimidazole

RAFT polymerization of N‐vinylimidazole followed pseudo‐first‐order kinetics. Morpholine‐based chain transfer agents for rapid polymerization of vinyl acetate afforded high‐molar‐mass poly(vinyl acetate) (up to 130 kg mol−1).