Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction
2009
This study describes a heteroligated, hemilabile PtII–P,S tweezer coordination complex that combines a chiral Jacobsen–Katsuki MnIII-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group.
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