Adlayers and Low-Dimensional Assemblies of a TTF Derivative at a Liquid−Solid Interface
2003
Scanning tunneling microscopy has been employed to investigate the ordering of a tetrathiafulvalene derivative at a liquid-solid interface at room temperature. Surprisingly, in addition to the observation of polymorphous two-dimensional pseudocrystals, lower-dimensional assemblies are observed. Scanning tunneling spectroscopy at the individual molecule level reveals rectifying behavior, independent of the molecular ordering.
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