Generation of Oxygen-Containing Radicals in the Aqueous Media of Mechanical Pulping
1995
Abstract Mechanical treatments of veratrylglycerol-β-syringaldehyde ether (M) were conducted with a ceramic ball mill or a vibration ball mill in the presence of water and n-paraffin alcohols which were used as ·OH scavengers. Addition of 1% each of the alcohols to the milling process of Compound (M) greatly decreased the yields of the products, e.g. veratryl alcohol 2, vanillin 3, syringaldehyde 4, 3,5-dimethoxy-p-benzoquinone 5, 3,5-dimethoxy-p-hydroquinone 6 and others. Another addition of n-paraffin alcohols to aqueous media during the millings also significantly reduced the concentration of H2O2. When phthalic hydrazide (P) was treated in the mills in the aqueous media, triacetoxyphthalazine (1A), 3-acetoxyphthalic acid (2A) and other products were separated from the acetates of the reaction mixtures. Results mentioned above disclosed the generation of ·O2H, ·OH, and ·H in the aqueous media during the mechanical treatments.
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
6
References
6
Citations
NaN
KQI