Conversion of 4-Methylanisole Catalyzed by Pt/γ-Al2O3 and by Pt/SiO2-Al2O3: Reaction Networks and Evidence of Oxygen Removal

The conversion of 4-methylanisole, a prototyp- ical bio-oil compound, was catalyzed by Pt/Al2O3, Pt/SiO2- Al2O3, or HY zeolite at 573 K and atmospheric pressure. More than a dozen products were formed with each catalyst, the most abundant being 4-methylphenol, 2,4-dimethyl- phenol, and 2,4,6-trimethylphenol; toluene was also a major product when the catalyst was supported platinum with H2 as a co-reactant. 4-Methylphenol was the only methylphenol isomer formed in significant yields, which indicates that migration of the methyl group on the aromatic ring is not significant under the selected reaction conditions. The data determine approximate reaction networks including reac- tions forming 4-methylphenol, 2,4-dimethylphenol, and toluene as primary products. The kinetically significant reaction classes were transalkylation, observed with all three catalysts, and hydrogenolysis (including hydrodeoxygen- ation) and hydrogenation, observed only with the platinum- containing catalysts operating in the presence of H2. Data such as those reported here provide a starting point for pre- dicting the conversion of whole bio-oils for removal of oxygen and upgrading of fuel properties.