Ytterbium(III) triflate-catalyzed electrophilic cyclization of glyoxalate-derived unsaturated imines
2002
Ytterbium(III) triflate was found to catalyze the electrophilic cyclization of some glyoxalate-derived unsaturated imines. The cyclization reactions gave exclusively fused amino γ-lactone products with good stereoselectivity. Moreover, a solid-phase version of the lanthanide-catalyzed reaction featured a lactonization with simultaneous cleavage of the product from the solid support.
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