Cationic polymer for selective removal of GenX and short-chain PFAS from surface waters and wastewaters at ng/L levels

Abstract The emerging classes of perfluorinated alkyl substances (PFAS) (e.g., Perfluorobutanoic acid (PFBA), perfluorobutane sulfonic acid (PFBS), GenX, ADONA, and F–53B) are persistent and recalcitrant to removal by conventional treatment techniques. Herein, we report on poly (N-[3-(dimethylamino)propyl]acrylamide, methyl chloride quaternary, DMAPAA-Q) hydrogel matrix as an effective sorbent for sequestering PFAS from different water matrices. The selective removal of 16 PFAS from different classes using DMAPAA-Q polymer was confirmed in surface waters and treated wastewater at environmentally relevant concentration (i.e.,  Cl− > NO3−. The performance of poly DMAPAA-Q hydrogel was maintained in six consecutive adsorption/regeneration cycles to remove PFAS. The unique fast kinetics and high adsorption activity of poly DMAPAA-Q hydrogel towards PFAS exhibits a great potential for being a promising material for PFAS control.