Comparison of AFS and ICP-MS detection coupled with gas chromatography for the determination of methylmercury in marine samples

Abstract Inductively coupled plasma mass spectrometry (ICP-MS) and atomic fluorescence spectrometry (AFS) coupled with gas chromatography (GC) have been evaluated as element specific detectors for the determination of methylmercury in marine samples. Detection limits for methylmercury chloride, obtained using ICP-MS and AFS, were 0.9 and 0.25 pg as Hg, respectively. Methylmercury was determined in marine tissue reference materials IAEA 142 and NIST 8044 mussel homogenate, and DOLT-2 dogfish liver by GC–AFS, with found values of 45±7, 26±4, and 671±41 ng g −1 , compared with certified values of 47±4, 28±2, and 693±53 ng g −1 . The analyses of IAEA 142 and NIST 8044 were repeated using GC–ICP-MS, with found values of 48±9 and 30±3 ng g −1 , respectively. Methylmercury was determined in real samples of ringed seal and beluga whale, with found values of 801±62 and 2830±113 ng g −1 , respectively.