Method and device for treating oil refining salt-containing sewage by using oil refining waste catalyst and ozone
2014
The invention provides a method and device for treating oil refining salt-containing sewage by using an oil refining waste catalyst and ozone. According to the method, the oil refining salt-containing sewage is subjected to catalytic oxidation treatment of internal circulation in a fluidized bed reactor by using ozone-containing gas and an activated oil refining waste catalyst, and the treated sewage flows through a vertical sedimentation basin and then is discharged outwards, wherein the CODcr (chemical oxygen demand) value of the effluent satisfies the primary standard A of Chinese Discharge Standard of Pollutants for Municipal Wastewater Treatment Plant (GB 18918-2002). The device is used for implementing the method, and at least comprises a fluidized bed reactor and a vertical sedimentation basin. According to the method and the device disclosed by the invention, the oil refining waste catalyst is used as a sewage ozone treatment cooperating catalyst, so that a utilization direction of 'waste control by waste' is provided for solid wastes of oil refining plants, and the problem of relatively high cost of a catalyst is solved; and the mass transfer effect among ozone, a catalyst and organic pollutants is strengthened by using a fluidization technology, and the problems that the utilization rate of ozone is relatively low and the catalyst is easy to scale are solved.
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