Energy Transfer and Optical Properties of Dendrimers

For dendrimers of various sizes the optical absorption is investigated theoretically. The molecular subunits of a dendrimer are modeled as two level systems. The electronic interaction between them is described via transfer integrals and the influence of vibrational degrees of freedom is taken into account in a first approach using a stochastic model. We show that rim states of the dendrimer dominate the absorption spectra, that in general the electronic excitation energy is concentrated on peripheric molecules, and that the energetically lowest absorption peak is redshifted with increasing dendrimer size due to delocalization of the electronic excitation.