Effect of Complex On Electrical Properties of Dendrimer Langmuir-Blodgett Films Containing 48 Pyridinealdoxime
2002
Dendrimers represent a new class of synthetic macromolecules characterized by a regularly branched treelike structure. Peculiar features of the dendritic geometry are the large number of end groups as well as the shape persistence in higher generations, approaching spherical geometry. And one of the most peculiar characteristics of dendritic macromolecules is their controlled molecular structure and orientation, which means that they have a practical application in achieving a highly organized molecular arrangement. We attempted to fabricate a G4-48PyA dendrimer Langmuir–Blodgett (LB) films containing 48 pyridinealdoxime functional end group that could form a complex structure with metal ions. Also, we investigated the surface activity of dendrimer films at air-water interface. And we have studied the electrical properties of the ultra-thin dendrimer LB films. The electrical properties of the ultra-thin dendrimer LB films were investigated by studying the current–voltage characteristics of metal/dendrimer LB films/metal (MIM) structure. The rectifying behavior of the devices was occurred in applied field. And result in change of electrical properties by the effect of complex with metal ions.
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