Hydrolysis of an iridium-methyl bond, formation of trans-[Ir(CO)(OH)L 2 ] from trans-[Ir(CO)MeL 2 ] [L = PPh 2 (m-C 6 H 4 SO 3 Na), PPh 2 (m-C 6 H 4 SO 3 K) or P(C 6 H 4 SO 3 Na) 3 ] upon dissolving in water