Study on chloro-substituted reaction of C_(12～24) n-alkanes

The characteristics of chloro-substituted reaction of C12～24 n-alkanes under the condition of heating,photocatalyis and chemical catalyis are studied,and the comparative analysis on the three methods is made.The influencial factors on chloro-substituted reaction of C12～24 n-alkanes under the condition of chemical catalyst are emphatically discussed.The optimal reaction conditions are as follows:12 hour of reaction time,70℃ of reaction temperature,1 wt% of the catalyst content,25 g/h of the feeding speed of chlorine.The research provides theoretical basis for mode selection of industrialized production of chlorinated hydrocarbons.