Mechanism of cadmium removal from soil by silicate composite biochar and its recycling.

Abstract Biochar added to the soil is generally difficult to separate. In order to solve the problem of separating biochar from soil, this paper applies a hydraulic silicate gel material to the preparation of biochar. Non-magnetic silicate bonded biochar (SBC) and magnetic silicate bonded biochar (MSBC) with hydraulic properties were prepared. The new silicate bonded biochar has good adsorption performance, separation and recovery characteristics. The findings are as follows: (1) after three times of soil remediation, the silicate bonded biochar still had good mechanical properties, and the compressive strength was not attenuated, remaining between 210 and 270 N. (2) After three times of SBC and MSBC remediation, total Cd in soil decreased by 29.33% and 31.82% respectively, and available Cd decreased by 60.82% and 62.74% respectively. (3) After three cycles, the recovery rates of SBC and MSBC both exceeded 94.88%, and the highest adsorption regeneration rates of SBC and MSBC reached 83.09% and 92.06%, respectively. (4) The Cd content of wheat after SBC and MSBC repair was reduced by 29.67–37.36% and 47.25–63.74%, respectively.