The Darasun gold deposit, Eastern Transbaikal region: Chemical composition, REE patterns, and stable carbon and oxygen isotopes of carbonates from ore veins

The chemistry, REE patterns, and carbon and oxygen isotopic compositions of carbonates from ore veins of the Darasun deposit are discussed. In addition to the earlier described siderite, calcite, and carbonates of the dolomite-ankerite series, kutnahorite is identified. The total REE content in Fe-Mg carbonates of the dolomite-ankerite series (2.8–73 ppm) is much lower than in later calcite (18–390 ppm). δ13C of Fe-Mg carbonates and calcite varies from +1.1 to −6.7‰ and from −0.9 to −4.9‰, respectively. δ18O of Fe-Mg carbonates and calcite varies from +17.6 to 3.6‰ and from +15.7 to −0.5‰, respectively. The REE sum and carbon and oxygen isotopic compositions reveal zonal distribution relative to the central granodiorite porphyry stock. The correlation between the carbon and oxygen isotopic compositions and REE sum reflects variations in the physicochemical formation conditions and composition of ore-forming fluid. The isotopic composition of fluid is calculated, and possible sources of its components are considered. Earlier established evidence for a magmatic source of ore-forming fluid and participation of meteoric water in ore formation is confirmed. Geochemical evidence for interaction of ore-forming fluid with host rocks is furnished. The relationships between the REE sum, on the one hand, and carbon and oxygen isotopic compositions of hydrothermal ore-forming fluid, on the other, are established.