A Novel Porphyrin Dye with Phenoxazine as Donor Unit for Efficient Dye-Sensitized Solar Cells

Abstract A novel porphyrin dye T-2 with phenoxazine (POZ) as donor unit has been synthesized and utilized for dye-sensitized solar cells (DSSC). Compare with porphyrin dye T-1 (in which triphenylamine as a donor unit), the DSSC based on T-2 exhibited a significantly higher Jsc (16.35 mA·cm-2) and Voc (670 mV) than that of T-1 (9.13 mA·cm-2, 610 mV), which attribute to the higher IPCE and τ of the device based on T-2. Correspondingly, the T-2-based device achieved a photoelectric conversion efficiency (PCE) of 7.64% (N719, 8.45%). By detailed investigation of the relationship between structure and performance, we found the butterfly-shaped structure, stronger electron-donating capability, and the extra alkyl chain of POZ are the main reasons leading to better performance of T-2 than that of T-1 in the DSSC device.