Oxygen containing tetrathiapentalene derivative having ethylthio chains
2003
Abstract An oxygen containing tetrathiapentalene (TTP) derivative with ethylthio chains, C 2 TEO-TTP has been synthesized. The charge-transfer complexes show two types of crystal forms and conducting behavior. (C 2 TEO-TTP) 2 X (X=PF 6 and AsF 6 ) have β-type structure and metallic conductivity down to liquid helium temperatures, and (C 2 TEO-TTP) 2 Au(CN) 2 has dimeric donor arrangement and its temperature dependence of conductivity undergoes a hysteric process.
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