Laser-generated liquid microjets: correlation between bubble dynamics and liquid ejection

Laser-based techniques provide excellent means for liquid microprinting, with several advantages over other more conventional printing techniques, such as being nozzle-free (as opposed to inkjet, for instance) or requiring minimal engineering of the liquid properties in the pre-printing stage. In such techniques, the transfer is usually mediated by liquid jets that contact a receiver substrate placed nearby the liquid source, leading to the deposition of a small droplet. The main cause of jetting lies in a laser-generated bubble produced inside the liquid, whose dynamics dictates the evolution of liquid ejection. However, the detailed relationship between the bubble and the jet is not completely understood, as the studies carried out so far have been mostly focused on the jetting dynamics taking place above the liquid free-surface, without access to the liquid interior and therefore to the behavior of the bubble. In this work, we analyze through time-resolved imaging the film-free laser printing of an aqueous solution by simultaneously visualizing both the bubble evolution and the liquid ejection dynamics, thus making possible the correlation between the two phenom- ena. We find that the pulsating behavior of the bubble leads to successive jetting events with different jet morphologies arising from the particular geometries that the bubble acquires during its evolution. Finally, we find good agreement between our results and those from studies analyzing the dynamics of cavitation bubbles near the free- surface of a liquid through numerical solution of the fluid dynamics equations.