Ligand-Free Palladium Catalyzed Phosphorylation of Aryl Iodides.
2016
A reusable ligand-free palladium catalyzed phosphorylation of aryl iodides using PdCl2/tetrabutylammonium bromide is described. Functionalized triarylphosphines were obtained in good to excellent yields in the absence of external reductants and supporting ligands.
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