Radical ring‐opening polymerization
2001
This chapter deals with radical ring-opening polymerization (radical ROP), which provides us with a strategy for synthesizing heteroatom-containing polymers by radical processes. Various cyclic monomers capable of radically induced ROP are introduced so that the essential items of molecular designs and polymerization mechanisms can be understood. Recent examples of controlled radical ROPs for well-defined polymer synthesis are also described.
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