Mitigating Structural Instability of High Energy Lithium and Manganese Rich LiNixMnyCoz Oxide by Interfacial Atomic Surface Reduction
2019
Surface modification of electrode materials using chemical treatments and atomic layer deposition is documented as an efficient method to stabilize the lattice structure as well as to reinforce the electrode/electrolyte interface. Nevertheless, expensive instrumentation and intrinsic deterioration of the material under high-temperature conditions and aggressive chemical treatments limit their practical application. Here, we report enhanced electrochemical stability and performances by simple atomic surface reduction (ASR) treatment of Li- and Mn-rich 0.35Li2MnO3·0.65LiNi0.35Mn0.45Co0.20O2 (HE-NMC). We provide mechanistic indications showing that ASR altered the electronic structure of surface Mn and Ni, leading to higher stability and reduced parasitic reactions. We demonstrate significant improvement in the battery performance with the proposed surface reduction, which is reflected by the enhanced capacity (290 mA h g–1), rate capabilities (∼15% enhancement at rates of 1 and 2 C), 50–60 mV narrow voltage...
Keywords:
- Correction
- Source
- Cite
- Save
- Machine Reading By IdeaReader
39
References
21
Citations
NaN
KQI