A new observation of limiting-case 1,3-dipolar cycloaddition. Evidence for a highly unsymmetrical transition-state structure with the reactions of mesoionic compounds

Brian P. Coppola,Mark C. Noe,Robert L. Ii. Abdon,Reed G. Konsler

A new observation of limiting-case 1,3-dipolar cycloaddition. Evidence for a highly unsymmetrical transition-state structure with the reactions of mesoionic compounds

1993

Brian P. Coppola
Mark C. Noe
Robert L. Ii. Abdon
Reed G. Konsler

Torsional restriction and a highly unsymmetrical transition state for a 1,3-dipolar cycloaddition divert a portion of the reaction through a stepwise pathway

Keywords:

Side reaction
Photochemistry
Cycloaddition
Acylation
Mesoionic
Bicyclic molecule
Limiting
Reactivity (chemistry)
1,3-Dipolar cycloaddition
Chemistry

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