Mechanism of Charge-transfer Polymerization. III. Flash Photolysis of N-Vinylcarbazole–Chloranil System

Yasuhiko Shirota,Kiyoshi Kawai,Naoto Yamamoto,Kazuhiro Tada,Tadamasa Shida,Hiroshi Mikawa,Hiroshi Tsubomura

Mechanism of Charge-transfer Polymerization. III. Flash Photolysis of N-Vinylcarbazole–Chloranil System

1972

Yasuhiko Shirota
Kiyoshi Kawai
Naoto Yamamoto
Kazuhiro Tada
Tadamasa Shida
Hiroshi Mikawa
Hiroshi Tsubomura

Photochemical formation of transient N-vinylcarbazole cation and chloranil anion-radicals has been demonstrated by means of flash spectroscopy for the N-vinylcarbazole–chloranil–solvent systems. Identification and decay of the species formed by flash illumination are described.

Keywords:

Spectroscopy
Flash photolysis
Chloranil
Inorganic chemistry
N-Vinylcarbazole
Polymerization
Organic chemistry
Photochemistry
Chemistry
flash spectroscopy

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