Scalable synthesis of monodisperse and recyclable sulfonated polystyrene microspheres for sustainable elimination of heavy metals in wastewater.

Herein, we demonstrate a scalable method for fabricating monodisperse sulfonated polystyrene (SPS) microspheres with abundant sulfonic acid groups and excellent heavy metal removal ability. A comprehensive characterization through SEM, EDS, FT-IR, TG, XRD and XPS confirmed the formation of the SPS microspheres. Take advantage of the abundant sulfonic acid groups on the surface of microspheres, as well as the superior monodisperse properties, adsorption ability of SPS microspheres both in quantity and speed have been enhanced. The adsorption equilibrium obeyed the Langmuir isotherm model with the theoretical maximum capacities of 49.16, 15.38 and 13.89 mg·g-1 for Pb2+, Zn2+ and Cu2+, respectively (30℃, pH=3.5). Besides, the adsorption equilibriums of Pb2+ onto SPS microspheres can be achieved within only 1 min and the adsorption kinetics can be fitted by a pseudo-second-order kinetics model. More importantly, because of the micron structure of the SPS microspheres, it could overcome the excessive hydrophilia brought by rich sulfonic acid groups and thereby easily separated, which maintain a good recyclable capacity after five regeneration cycles. With the excellent adsorption ability and reusability, SPS microspheres can efficiently handle the polluted water in a convenience and rapid process, which satisfies the sustainable pollution treatment in heavy metals elimination. GRAPHICAL ABSTRACT