Investigation of non-uniformity and inclusions in 6LiInSe2 utilizing Laser Induced Breakdown Spectroscopy (LIBS)
2013
Impurity analysis and compositional distribution studies have been conducted on a crystal of
LiInSe 2 , a compound semiconductor which recently has been shown to respond to ionizing radiation.
IR microscopy and laser induced breakdown spectroscopy (LIBS) revealed the presence of
inclusions within the crystal lattice. These precipitates were revealed to be alkali and alkaline earth
elemental impurities with non-uniform spatial distribution in the crystal. LIBS compositional maps
correlate the presence of these impurities with visual color differences in the crystal as well as a
significant shift of the band gap. Further, LIBS revealed variation in the ratio of I-III-VI2 elemental
constituents throughout the crystal. Analysis of compositional variation and impurities will aid in
discerning optimal synthesis and crystal growth parameters to maximize the mobility-lifetime
product and charge collection efficiency in the LiInSe 2 crystal. Preliminary charge trapping
calculations have also been conducted with the Monte Carlo N-particle eXtended (MCNPx) package
indicating preferential trapping of holes during irradiation with thermal neutrons.
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