A Tetratopic Phosphonic Acid for the Synthesis of Permanently Porous MOFs: Reactor Size-Dependent Product Formation and Crystal Structure Elucidation via Three-Dimensional Electron Diffraction.

Following the strategy of installing porosity in coordination polymers predefined by linker geometry, we employed the new tetratopic linker molecule 1,1,2,2-tetrakis[4-phosphonophenyl]ethylene (H8T...