Lewis acid-catalyzed unexpected selective C-C bond cleavage: an efficient and mild construction of cyclopentenes
2012
An intriguing Lewis acid-catalyzed intramolecular ring-opening/cyclization reaction of cyclopropylvinylallenes is developed. This process proceeds at ambient temperature to afford the structurally diverse cyclopentenes exclusively, which demonstrates the unique reactivity of 1,3,4-alkatrien-2-yl cyclopropanes.
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