Synthesis methods of tri-(4-triazolyl phenyl) amine and tri-(4-triazolyl phenyl)amine cadmium complex
2014
The invention discloses synthesis methods of a tri-(4-triazolyl phenyl) amine and a tri-(4-triazolyl phenyl) amine cadmium complex, and relates to the field of luminescent materials. The synthesis method of the tri-(4-triazolyl phenyl) amine takes copper oxide as a catalyst and dimethylsulfoxide as a solvent, tri-(4-iodobenzene) amine and triazole react at the temperature of 120-170 DEG C, then the mixture is diluted by the solvent, filtered, decolored, separated and purified sequentially to obtain the tri-(4-triazolyl phenyl) amine; the synthesis method of the cadmium complex is carried out by mixing 5-aminoisophthalic acid, 3-(4-triazolyl phenyl) amine and cadmium acetate into a mixed solution of water and alcohol, then the mixture is uniformly stirred under the acid or neutral condition to obtain a reaction liquid, and the reaction liquid is put into a reaction kettle to crystalize and react to obtain the tri-(4-triazolyl phenyl) amine cadmium complex. The synthesis methods obtain the tri-(4-triazolyl phenyl) amine and the tri-(4-triazolyl phenyl) amine cadmium complex, whose crystal purities are more than 95% and whose yields are more than 85%, through the simple synthesis route.
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