Vanadium/cobalt oxides–anchored flexible carbon nanofibers with tunable magnetism as recoverable peroxidase-like catalysts

Abstract High-efficiency peroxidase-like catalysts that can be easily recycled are desperately needed for the rapid and accurate detection of H2O2. Herein, a novel flexible membrane composed of vanadium/cobalt oxides–anchored carbon (VCoO/C) nanofibers has been purposely designed and fabricated by electrospinning and subsequent carbonization, where there are processing temperature-dependent morphology, composition, and versatile properties. As the carbonization temperature increases from 600°C to 900°C, the saturation magnetization of the as-prepared VCoO/C nanofibers rises gradually. When treated at 750°C under Ar protection, the resultant VCoO/C-750 nanofibers yield superior peroxidase-like catalytic activity toward H2O2 with a low limit of detection of 0.44 μM (signal-to-noise ratio = 3). The combination of magnetic behavior and flexibility enables the effective recovery of catalysts. It is believed that our results will open a new avenue for the controlled preparation of flexible nanofiber materials, which are endowed with multiple functions.