Effects of pressure on structure and extinction limits of counterflow nonpremixed water-laden methane/air flames

Abstract Structure and extinction limits of counterflow nonpremixed water (H 2 O)-laden methane (CH 4 )/air flames at various pressures are computationally investigated to better understand combustion processes of fuel having naturally high H 2 O (vapor) content under elevated pressures. Using a detailed kinetic mechanism and a statistical narrow-band radiation model, the flame structure and extinction limits are predicted for elevated pressures and a wide range of flame strain rates and compared with those at atmospheric pressure. Results show that with increasing pressure the maximum flame temperature increases and the extinction limits are generally extended due to the reduced amount of dissociation and the enhanced radiation reabsorption of H 2 O, indicating that flames can sustain more H 2 O vapor at elevated pressure. The concentration of active radicals and the flame thickness decrease with increasing pressure. The observed flammable range of the H 2 O to CH 4 molar ratio at elevated pressures is comparable to that found in self-sustained combustion of CH 4 hydrates at atmospheric pressure, and the chemical effects of H 2 O addition on flame structure are insignificant. Elevated pressure enhances the formation of soot precursors such as acetylene (C 2 H 2 ), implying an opposite tendency from the water addition effects.