A novel narrow band UV-B emitting phosphor-YPO_4:Sb~(3+),Gd~3

2016 
YPO_4 phosphors single-doped with Sb~(3+) or Gd~(3+) and co-doped with Sb~(3+) and Gd~(3+) were prepared by a solid-state reaction method. The phase purity, morphology, photoluminescence excitation and emission properties of the prepared phosphors were investigated. The results showed that Sb~(3+) could sensitize Gd~(3+) in the co-doped phosphors which made the phosphors excitable by short-wave ultraviolet(UV) at a wavelength between 220 and 260 nm. Under 253.7 nm excitation, the co-doped phosphors Y_(1–x–y) PO_4: Sb~(3+)x,Gd~(3+)y showed strong emission of Gd~(3+) at a wavelength of 312 nm whose intensity changed with the doping concentrations of Gd~(3+) and Sb~(3+). The optimized Y_(0.77)PO_4:Sb~(3+)0.07,Gd~(3+)0.16 phosphor showed an intensity comparable to commercial LaPO_4:Ce phosphor(UVB-315), making it a potential candidate for mercury low-pressure discharge narrow-band UV-B emitting lamps.
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