In situ growth of graphdiyne based heterostructure: Toward efficient overall water splitting

Abstract The controlled synthesis of graphdiyne-wrapped cobalt nitride nanosheets and their direct application as a bifunctional electrocatalyst towards electrical splitting water was reported for the first time. Because of its unique electronic and chemical structure, the electrocatalyst has high activity and stability in electrocatalysis process of 1.0 M KOH. The catalyst embedded by graphdiyne showed excellent catalytic performance of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER) with low overpotentials of 70 mV and 260 mV, respectively, at 10 mA cm −2 , which was obviously superior to that of the commercial Pt/C and RuO 2 , respectively. As both the anode and cathode in a two-electrode alkaline electrolyzer, 10 mA cm −2 can be obtained at an ultralow cell voltage of 1.48 V which is much smaller than that of Pt/C RuO 2 couple.