N-Heterocyclic Carbenes by Tautomerization of Mesomeric Betaines. Thione, Selenone, and Borane Adduct Formations of Imidazolium-Isocytosinates.

Jiaxi Zhang,Matthias Franz,Eike Huebner,Andreas Schmidt

N-Heterocyclic Carbenes by Tautomerization of Mesomeric Betaines. Thione, Selenone, and Borane Adduct Formations of Imidazolium-Isocytosinates.

2016

Jiaxi Zhang
Matthias Franz
Eike Huebner
Andreas Schmidt

Basic treatment of imidazolium isocytosinates (III) leads to cross-conjugated heterocyclic mesomeric betaines which are in equilibrium with their corresponding carbenes (IV).

Keywords:

Tautomer
Medicinal chemistry
Borane
Adduct
Organic chemistry
Chemistry

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