Organotemplate-free Hydrothermal Synthesis of SUZ-4 Zeolite: Influence of Synthesis Conditions

Abstract Various conditions were investigated in detail for the novel organic template-free static hydrothermal synthesis of SUZ-4 zeolite in the presence of seeds. The obtained samples were characterized by XRD (X-ray diffraction), SEM (scanning electron microscope), TG (thermal gravimetric analysis), ICP (inductively coupling plasma) elemental analysis, nitrogen sorption isotherm and surface area. The results show that pure SUZ-4 zeolites with high crystallinity are obtained in a broad window of synthesis conditions: seed mass concentration 0.2%–2%, SiO 2 /Al 2 O 3 molar ratio 21–25, KOH/SiO 2 molar ratio 0.33–0.43, H 2 O/SiO 2 molar ratio 7.14–38.1, aging time 24 h, crystallization temperature 160 °C, and crystallization time 6–10 d. Also, crystallinity and size of the rod-like SUZ-4 zeolite crystals are found to alter with the conditions.