Stereoselective Rh2(S‐IBAZ)4‐Catalyzed Cyclopropanation of Alkenes, Alkynes, and Allenes: Asymmetric Synthesis of Diacceptor Cyclopropylphosphonates and Alkylidenecyclopropanes.

2013 
This is the first catalytic asymmetric cyclopropanation of allenes with diacceptor diazo compounds.
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