Discovery of a bi-critical point between antiferromagnetic and superconducting phases in pressurized single crystal Ca0.73La0.27FeAs2

One of the most strikingly universal features of high temperature superconductors is the superconducting phase emerging in the close proximity of the antiferromagnetic phase, and the interplay between these two phases poses a long-standing challenge to condensed matter physicists. It is commonly believed that, as the antiferromagnetic transition temperature is suppressed to zero, there appears a quantum critical point and the antiferromagnetic fluctuation around the quantum critical point is responsible for the development of unconventional superconductivity. Here we report that, in contrast to this scenario, the discovery of a direct first-order phase transition with a bi-critical point between the antiferromagnetic metallic phase and superconducting phase in the pressurized high-quality single crystal Ca0.73La0.27FeAs2, which is the parent compound of a newly discovered iorn pnictide superconductors with unusual intercalated layers. By advanced in-situ high pressure measurements of electrical resistivity, alternating current susceptibility, heat capacity and synchrotron x-ray diffraction, we observed that, upon increasing pressure, the superconducting phase with transition temperature 25.8 K suddenly appears at 2.99 GPa and then increases slightly after the antiferromagnetic transition temperature is continuously suppressed and disappears at 26.2 K and 2.80 GPa, from which the bi-critical point is identified at 2.90 GPa and 25.2 K. The discovery of the bi-critical point provides an alternative picture to understand the interplay between antiferromagnetism and superconductivity, and revives the unified theory of the antiferromagnetism and superconductivity proposed twenty years ago for the high temperature copper oxide superconductors.