Palladium‐Catalyzed Divergent Reactions of α‐Diazocarbonyl Compounds with Allylic Esters: Construction of Quaternary Carbon Centers

Zi-Sheng Chen,Xin-Hua Duan,Ping-Xin Zhou,Shaukat Ali,Jian-Yi Luo,Yong min Liang

Palladium‐Catalyzed Divergent Reactions of α‐Diazocarbonyl Compounds with Allylic Esters: Construction of Quaternary Carbon Centers

2012

Zi-Sheng Chen
Xin-Hua Duan
Ping-Xin Zhou
Shaukat Ali
Jian-Yi Luo
Yong min Liang

Allyl arylpropiolates react with the diazo compounds to give 1,5-enynes (III) bearing an all-carbon quaternary center via palladium-catalyzed decarboxylation and migratory insertion.

Keywords:

Migratory insertion
Diazo
Allylic rearrangement
Homogeneous catalysis
Palladium
Catalysis
Organic chemistry
Carbon
Decarboxylation
Inorganic chemistry
Chemistry
quaternary carbon

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